1. China - 9056.8MT (Metric Megatons)
2. United States of America - 4833.1 MT
3. India - 2076.8MT
4. Russian Federation - 1438.6MT
Of the four top ranking polluters of CO2 the USA is the ONLY First World country.
I take issue with US Senator Bernie Sanders when it comes to what countries are most responsible for CO2 emissions. The USA as of 2016 was still number two and only preceded by China, still considered an emerging economy.
When, not if, the USA achieves zero greenhouse gas emissions, it will end 16% of CO2 emissions and below the USA is ranked 4th among the top 4 methane emission countries.
Methane emissions (kt (kiloton) of CO2 equivalent) - Country Ranking